From context I think it’s pretty clear that they meant they fit well together.
He made that statement and then right after explained a situation that enforces what he meant. Paraphrasing: “we shipped them together. Before they made it official. (so we knew before hand, what else could that mean? They’re at a wedding.) he scoffed at the idea. (he didn’t think they fit together, while his friends did.)”
From context I think it’s pretty clear that they meant they fit well together. He made that statement and then right after explained a situation that enforces what he meant. Paraphrasing: “we shipped them together. Before they made it official. (so we knew before hand, what else could that mean? They’re at a wedding.) he scoffed at the idea. (he didn’t think they fit together, while his friends did.)”